G-band resonant Raman study of 62 isolated single-wall carbon nanotubes

Resonance Raman Spectroscopy of Single-Walled Carbon Nanotubes

The unusual one-dimensional properties of phonons in crystalline arrays of carbon nanotubes is presented. The main technique for probing the phonon spectra is Raman spectroscopy and the many unique and unusual features of the Raman spectra of carbon nanotubes are highlighted. Various features of the first-order Raman spectra are emphasized, with regard to their 1D behavior and special character...

Electronic transition energy Eii for an isolated (n,m) single-wall carbon nanotube obtained by anti-Stokes/Stokes resonant Raman intensity ratio

Resonance Raman spectra of carbon nanotubes by cross-polarized light.

Resonance Raman studies on single wall carbon nanotubes (SWNTs) show that resonance with cross polarized light, i.e., with the E(mu,mu+/-1) van Hove singularities in the joint density of states needs to be taken into account when analyzing the Raman and optical absorption spectra from isolated SWNTs. This study is performed by analyzing the polarization, laser energy, and diameter dependence of...

Resonant Raman spectroscopy of individual strained single-wall carbon nanotubes.

Resonance Raman spectra of individual strained ultralong single-wall carbon nanotubes (SWNTs) are studied. Torsional and uniaxial strains are introduced by atomic force microscopy manipulation. Torsional strain strongly affects the Raman spectra, inducing a large downshift in the E2 symmetry mode in the G+ band, but a slight upshift for the rest of the G modes and also an upshift in the radial ...

Structural ( n, m) determination of isolated single-wall carbon nanotubes by resonant Raman scattering.

We show that the Raman scattering technique can give complete structural information for one-dimensional systems, such as carbon nanotubes. Resonant confocal micro-Raman spectroscopy of an (n,m) individual single-wall nanotube makes it possible to assign its chirality uniquely by measuring one radial breathing mode frequency omega(RBM) and using the theory of resonant transitions. A unique chir...